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課程名稱 |
物理化學一-熱力學
Physical Chemistry (Ⅰ)-Thermodynamics |
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開課學期 |
101-1 |
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授課對象 |
理學院 化學系 |
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授課教師 |
陸駿逸 |
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課號 |
Chem3030 |
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課程識別碼 |
203 33160 |
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班次 |
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學分 |
3 |
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全/半年 |
半年 |
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必/選修 |
必修 |
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上課時間 |
星期三2(9:10~10:00)星期五3,4(10:20~12:10) |
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上課地點 |
化210室化210室 |
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備註 |
1.先修普化甲/普物甲/微積分甲。2.詳選課須知。
限學士班三年級以上 且 限本系所學生(含輔系、雙修生)
總人數上限：80人 |
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Ceiba 課程網頁 |
http://ceiba.ntu.edu.tw/1011PChem1 |
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課程簡介影片 |
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核心能力關聯 |
核心能力與課程規劃關聯圖 |
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課程大綱
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課程概述 |
This course will cover the following topics: basic concepts of thermodynamics and statistical thermodynamics, chemical equilibrium and electrochemical equilibrium, phase transition, diffusion.
The course will contain the following topics. The materials with * will depend on the available time.
Chapters 1-7,
1. temperature, equations of state
2. 1st law,
3. 2nd and third laws,
4. Fundamental equation of thermodynamics,
5. chemical equilibrium,
16. Statistical Mechanics (ideal gas, internal degrees of freedom, solid, Debye model)
Statistical Mechanics of Van der Waals liquid
6. phase equilibrium,
7. electrochemistry and Debye Huckel, electrophoresis
* 21. Macromolecules (Rg, freely rotation model, excluded volume, coil-globule transition)
* 20. Liquid (diffusion) (Langevin equation, diffusion equation, dynamic light scattering)
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課程目標 |
Establish important thermodynamics concepts and their microscopic interpretations. |
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課程要求 |
Home work + one midterm and the final exams. |
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預期每週課後學習時數 |
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Office Hours |
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指定閱讀 |
Physical Chemistry
by Robert J. Silbey, Robert A. Alberty and Moungi G. Bawendi (2004)
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參考書目 |
To come. |
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評量方式
(僅供參考) |
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No. |
項目 |
百分比 |
說明 |
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1. |
home work |
40% |
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2. |
midterm exam |
30% |
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3. |
final exam |
30% |
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週次 |
日期 |
單元主題 |
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第1週 |
9/12,9/14 |
Zeroth law of thermodynamics, equation of state
習題 1.7, 1.8, 1.9, 1.10, 1.11, 1.17, 1.18, 1.B, 1.C (9/24 交) |
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第2週 |
9/19,9/21 |
van der Waals' equation, number of variables, Euler's theorem, barometric formula, work, 1st law, exact differential |
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第3週 |
9/26,9/28 |
more works, reversible path, Cv, Cp, ideal gas, adiabatic process, Joule-Thomson expansion, enthalpy of reaction |
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第4週 |
10/03,10/05 |
Carnot cycle, 2nd laws (Clausius,Kelvin), Carnot theorem, thermodynamic temperature scale, Clausius inequality |
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第5週 |
10/10,10/12 |
entropy, Caratheodory theory |
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第6週 |
10/17,10/19 |
ideal gas entropy, Cv of solid, entropy of mixing, Gibbs' paradox, Nernst's theorem, third law of thermodynamics |
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第8週 |
10/31,11/02 |
U, A, G min, Gibbs-Helmholtz equation, Gibbs-Duhem equation, Maxwell relations, 習題: 4.2,4.16, 4.17, 4.21,4.24, 4.29, 4.30, 4.32, 4.38 |
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第10週 |
11/14,11/16 |
Chemical equilibrium, K, Boltzmann entropy formula 習題：5.5, 5.17, 5.23, 5.27, 5.38, 5.72, 5.74, 5.80 |
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第11週 |
11/21,11/23 |
microcanonical ensemble, ideal gas entropy formula |
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第12週 |
11/28,11/30 |
Boltzmann factor, Equipartition, Eistein model of solid 習題：Callen 15.2-1, 15.2-3 |
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第13週 |
12/05,12/07 |
Einstein model of solid, crystal vibration modes, Debye model |
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第14週 |
12/12,12/14 |
Debye model (correcting the errors in the previous notes), (The A in problem 15.2-3 is a constant.) |
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第15週 |
12/19,12/21 |
partition function, Gibbs' entropy formula, ideal gas (again), van der Waals' model, the meaning of a & b, the free energy of coexisting two phases |
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第16週 |
12/26,12/28 |
Clapeyron equation, Raoult's law, ideal solution
習題：6.2, 6.8, 6.26, 6.29, 6.B |
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第17週 |
1/02,1/04 |
phase diagrams, colligative properties, surface tension, Kelvin equation, Wulff construction of crystal shape (Ref. by Ringe, and DebyeHuckel are not the exam materials.) |
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